• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to a method for manufacturing a one-way vision glass panel comprising one or more discrete enamel patterns, composed of several layers in exact coincidence, characterized in that: a) is deposited on the substrate at least one protective layer based on oxides with a thickness greater than or equal to 10 nm, b) at least two layers of different composition are deposited on the protective layer, the composition of the one containing at least a mineral pigment and being free of glass frit, the composition of the other being an enamel containing at least one glass frit and at least one mineral pigment of a different color from that of the glass frit-free layer, the free layer glass frit being deposited on all or part of the surface of the panel and the enamel layer being deposited by screen printing in the form of the desired pattern or patterns, c) the coated panel is heated said layers at a temperature sufficient to bake the enamel, and d) removing non-enamel-bound pigments located outside the pattern (s), the pigment particles (s) and the sintered particles (s). ) of glass having a similar size, especially a particle size distribution such that 50% of the particles have a size less than 7 microns.
    公开号:FR3020360A1
    申请号:FR1453709
    申请日:2014-04-24
    公开日:2015-10-30
    发明作者:Kamel Chahboune；Elodie Ducourthial
    申请人:Saint Gobain Glass France SAS；Compagnie de Saint Gobain SA；
    IPC主号:
    专利说明:

    [0001] The present invention relates to the field of printed glass substrates comprising enamel - based patterns. The printed glass substrates are used in a variety of applications for decorative purposes and! or functional, for example as glazing for buildings or automobiles. Patent application WO 2012/172269 describes a method of manufacturing a one way vision glass panel. This type of glazing allows an observer inside a building or vehicle to have a normal view of the outside environment, while an outside observer will have no vision on the inside. Such glazings are obtained by applying a first layer of pigments, often of a black color, free of glass frit, directly on the glass substrate in the form of the desired patterns, then depositing a second layer of enamel comprising a glass frit and pigments of a light color different from black, for example white, on all the patterns. The whole is brought to a temperature sufficient to cook the enamel. During the firing phase of the enamel, the glass frit present in the second enamel layer softens and clings to the substrate glass retaining the black pigments. After firing, the black pigments deposited outside the patterns, not fixed by the enamel, are removed by appropriate treatment, for example by vacuum suction or by application of an air jet or water. To prevent the migration of black pigments in a light-colored layer such as white and thus prevent the white is perceived with a greyish hue, the application WO 2012/172269 proposes on the one hand to use pigments and glass frits whose particles have a similar dimension, and secondly to deposit a thicker thickness of the second layer of enamel, the thickness of the pigment layer before firing or heating being between 4 and 15 pm and the thickness the enamel layer before firing or heating being between 20 and 100 pm. The step of fixing the pigments on the glass is carried out by baking which is generally carried out between 600 and 700 ° C. a, it turns out that some samples remain tinted after cooking, especially because of the migration of certain compounds of the black pigments, in places that have not been covered by white enamel. This tinted appearance is all the more marked that the temperature at which the cooking was performed is high. Even after cleaning the glass substrate, this black coloration does not disappear and is probably due to a migration of black pigments to the glass surface. The color of the glass is however not permanent and it disappears by leaching or chemical attack, for example by acid attack. However, this variation in hue depending on the cooking and time does not provide a stable product throughout the life of the product. The present invention overcomes the disadvantages explained above.
    [0002] The present invention relates to a method for manufacturing a one-way vision glass panel comprising one or more discrete enamel patterns, composed of several layers in exact coincidence, the method according to which: a) it is deposited on the glass substrate at least one protective layer based on oxides with a thickness greater than or equal to 10 nm, b) depositing on the protective layer at least two layers of different composition, the composition of one of the layers containing at least a mineral pigment and being free of glass frit, the composition of the other layer being an enamel containing at least one glass frit and at least one mineral pigment of a different color from that of the glass frit-free layer, the layer free of glass frit being deposited on all or part of the surface of the panel and the enamel layer being deposited by screen printing in the form of the desired pattern or patterns, c) heating the glass frit coated with said layers at a temperature sufficient to cook the enamel, and d) removing non-enamel-fixed pigments located outside the pattern (s), the pigment particles (s) and the sintered particles. (s) glass having a similar dimension, especially a particle size distribution such that 50% of the particles have a size less than 7 pm. in a first embodiment, during step b), the layer free of glass frit is deposited on the protective layer to a thickness of between 4 and 15 μm, over all or part of the surface of the panel, and then serigraphically depositing the enamel layer to a thickness of between 20 and 100 μm in the form of the desired pattern (s). in another embodiment, during step b), the enamel layer is deposited on the protective layer to a thickness of between 10 and 100 μm in the form of the desired pattern or patterns, and the layer is then deposited. free of glass frit to a thickness of between 4 and 30 μm, over all or part of the surface of the panel. The thicknesses given for each of the layers deposited during step b) are measured on wet layers, that is to say before the firing step c). Each successive deposition of the layers made in step b) is advantageously followed by a heat treatment step before depositing the second layer. The temperature of this treatment generally ranges from 70 to 150 ° C, and is preferably at least 110 ° C. The treatment can be carried out according to a method known to those skilled in the art, for example by means of infrared radiation lamps. The fact of depositing a protective layer on the glass substrate, before depositing the mineral pigment and the enamel layer, advantageously makes it possible to improve or even eliminate the gray tint that could be observed after cooking in the glass processes. the prior art. The protective layer acts as a barrier layer during the firing step and prevents migration of the pigment to the substrate and therefore undesired coloring thereof.
    [0003] Preferably, the protective layer deposited in step a) of the process according to the invention is a layer of silicon oxide or titanium oxide. Even more preferably, the protective layer is a silicon oxide layer. It can for example be deposited by magnetron. This type of layer has the advantage of being transparent and neutral and therefore not to modify the coloration of the substrate, nor the optical properties of the substrate coated with the protective layer. Magnetron deposition makes it possible to obtain a sufficiently dense layer which fulfills its role as a protective layer.
    [0004] The protective layer has the advantage of being resistant in time and aging. Preferably, the thickness of the protective layer is between 10 and 150 nm. Even more preferably, it is between 20 and 100 nm. In one embodiment, step a) of the process according to the invention may consist in depositing two successive layers based on oxides of different types and thicknesses. Depending on the protective layer chosen, it is possible to give a slight color to the coated substrate. Ansi deposition of a protective layer of titanium oxide to give a slightly yellow color to the coated substrate. Unlike the gray color undesired observed in the processes of the prior art, this coloration is homogeneous regardless of the enamel firing temperature and is stable over time.
    [0005] The deposition of the glass frit-free pigment layer produced in step b) can be done by any means known to those skilled in the art, in particular by screen printing, flat or rotary. The mineral pigment is preferably chosen from pigments which make it possible to impart a black color after the firing step. By way of examples, mention may be made of pigments based on chromium, iron, manganese, copper and! or cobalt, especially in the form of oxides or sulfides. Although chromium-based pigments provide an intense black color, they are not preferred because of problems related to their potential toxicity and their recycling. Thus, preferably, the inorganic pigment used in the glass frit-free layer is free of chromium. Advantageously, the black mineral pigment has a clarity L * as defined in the CIE Lab chromatic representation model (1931) which is less than or equal to 15, preferably less than or equal to 10, measured on the final glass panel. When the deposit is made by screen printing, the pigment is generally mixed with an organic medium that adjusts the viscosity so that the passage of the mixture through the mesh of the screen screen can be done properly. The viscosity of the mixture generally varies from 80 to 120 Poises, preferably of the order of 100 Poises. The organic medium also has the function of ensuring a temporary fixation of the pigments until the application of the following layer of enamel composition. The organic medium must be removed from the beginning of the enamel baking step to avoid the appearance of pores and cracks in the final enamel. It is generally an organic solvent, preferably based on a mixture of "heavy" or terpenic alcohols ("pine oil"), optionally combined with one or more resins that reinforce the temporary fixing of the pigment on the surface of the panel. Preferably, the thickness of the glass frit-free pigment layer deposited on the glass panel varies from 6 to 10 μm. The deposit of the enamel composition is performed by screen printing. Screen printing is a well-known printing technique that uses a silk screen made of a fabric on which the pattern (s) to be printed are (are) reproduced (s) and a rake to apply a force sufficient shear to pass the enamel composition through the mesh of the screen through the openings corresponding to the pattern (s) to be printed and deposit it on a support. The screen screen must have a mesh opening compatible with the size of the particles contained in the enamel composition. The son constituting said screen may be son steel or a polymeric material, for example polyester. The number of threads per centimeter generally ranges from 120 to 180 and preferably is of the order of 150. Preferably, the diameter of the threads ranges from 25 to 35 μm. The enamel screen printing composition is obtained by mixing the glass frit and the mineral pigment with an organic medium as defined above. By "glass frit" is meant a vitrifiable composition in the form of powder and based on oxides. According to the process according to the invention, the glass frit is in the form of particles having a size comparable to that of the pigment particles used in step b). Thanks to the small size of its particles combined with a low softening temperature, the glass frit can easily migrate to the panel surface by including the pigments which are thus firmly and durably bonded to the glass. The glass frit used in the process according to the invention is free of lead oxide Pb0 for reasons related to the preservation of the environment. Preferably, the glass frit is a borosilicate based on Bi203 bismuth oxide and / or zinc oxide ZnO. For example, the glass frit based on Bi 2 O 3 contains 35 to 75% by weight of 902 and 20 to 40% by weight of Bi 2 O 3 and advantageously 25 to 30%. Such a glass frit has a softening temperature which varies from 550 to 580 ° C, preferably is 568 ° C. For example, the ZnO glass frit contains 35 to 75% by weight of 902 and 4 to 10% by weight of ZnO. Such a glass frit has a softening temperature of less than 600 ° C, which varies from 560 to 590 ° C, preferably 577 ° C. As already indicated, the inorganic pigment included in the enamel layer has a different color from the pigment used in the glass frit-free layer and preferentially confers a different color from the black. Preferably, the pigment is chosen so that it is white in color after the c) step. This pigment is in particular titanium oxide TiO 2. Advantageously, the white mineral pigment has a clarity L * as defined in the CIE Lab (1931) chromatic representation model which varies from 65 to 85, measured on the final glass panel. The pigment may be of a different color than white, and is for example based on 0203 (green color), 00304 (blue color) or Fe203 (orange color). The proportion of pigments in the glass frit composition ranges from 5 to 25% by weight, preferably 10 to 20%. The viscosity of the mixture comprising the glass frit, the inorganic pigment and the organic medium generally ranges from 100 to 300. Poles, preferably 180 to 200 poles.
    [0006] Preferably, the thickness of the enamel layer deposited on the pigment layer varies from 10 to 100 μm, preferably 20 to 80 μm. Optionally, it is possible to apply to the enamel layer, before the firing step c), an additional layer of pigments of different color pigments present in the first layer and the enamel layer. This additional layer is generally applied so that it partially overlaps the surface of the enamel layer, which makes it possible to obtain more or less complex polychromatic patterns. If appropriate, after a layer has been deposited and before the application of the next layer, it may be applied heat treatment to reduce the amount of organic medium. The treatment temperature is generally from 70 to 150 ° C, and preferably is at least 110 ° C. The treatment can be carried out according to a method known to those skilled in the art, for example by means of infrared radiation lamps.
    [0007] In step c) of the process according to the present invention, the glass panel is treated at a so-called "firing temperature" which allows the glass frit to melt to form a layer of glass which fixes the pigment particles to the glass. panel surface. In the field of enamels, the firing temperature is the minimum temperature at which "sufficient" sintering of the enamel composition is observed, this sufficient sintering being reflected in particular by a strong bonding to the glass of the panel. The person skilled in the art can measure this cooking temperature, for example by passing on the surface of the enamel (after it has been brought to the treatment temperature and then cooled) a pen comprising a metal point connected to a spring that delivers a force of 20 Newtons and noting the lowest treatment temperature for which the enamel can not be removed from the glass. The firing temperature must be sufficiently high to cook the glass frit and possibly soak the glass, but not too large so that the glass sheet does not have undesirable apparent deformations. In general, the firing temperature ranges from 620 to 700 ° C, preferably from 640 to 660 ° C. In the cleaning step d), the pigments which lie outside the silkscreened patterns and which have not been fixed by the enamel are eliminated. Their removal can be carried out by any known means, for example mechanical, especially by creasing, dry or wet brushing, or water jet. The printed glass panel obtained by the process according to the invention can be used alone; in this case it is preferable that the panel has been previously thermally treated under temperature conditions such that the final glass is at least cured, and preferably soaked, so that said panel can be used safely. The glass panel obtained by the process according to the invention may consist of any type of glass, for example a silico-soda-lime glass, in particular obtained by the Float process. In general, it is a glass sheet whose thickness may vary to a large extent depending on the intended application. As an indication for a panel intended to enter into the constitution of a building glazing, this thickness varies from 2 to 20 mm, preferably 4 to 12. Preferably, especially for reasons of safety of persons, the glass panel is associated with one or more sheets of glass, in particular as defined above, by means of one or more sheets of a thermoplastic material having hot adhesive properties to form a laminated glass panel. By way of example of a sheet of thermoplastic material, mention may be made of polyvinyl butyral butyrate (PVB), ethylene-vinyl acetate (EVA), polyurethane and polycarbonate sheets. The number of sheets of glass in the laminated panel is a function of its size and the mechanical stress to which it is subjected. In general, the laminated panel comprises at most 6 glass sheets including the printed glass panel, and preferably 2 to 4 sheets of glass. The combination of the printed panel and the glass sheets with the sheets of thermoplastic material is carried out according to known methods, in particular using an autoclave. The invention is illustrated by means of the following nonlimiting examples and the attached figures in which: FIG. 1 represents a PLANILUXO float glass on which a black pigment has been deposited and which has been baked at temperatures varying between 600 and 700 ° C. FIG. 2 shows various float PLANILUXO glass substrates on which a protective layer of silicon oxide has optionally been deposited with different thicknesses. FIG. 3 represents a pattern printed on a PLANILUXO float glass substrate with or without a protective layer. FIG. 4 represents various float PLANILUXO glass substrates on which a layer of silicon oxide has been deposited by various processes and then coated with black pigments. Example 1: A black pigment free of chromium is deposited by the so-called screen printing process, using a screen 150.27 (150 being the number of threads cm and 27 being the thickness in μm of the polyester thread constituting the screen) on a PLANILUXO type glass substrate. The deposited thickness is 6 μm: it is measured with a laser perthometer just after the screen-printing step and before drying at 140 ° C. This black pigment-coated substrate is then fired in a gradient oven at temperatures between 600 and 700 ° C followed by cleaning of the fired glass. The photo of the substrate obtained after firing and cleaning is given in FIG. 1. There is clearly a color gradient related to the more or less significant migration as a function of the temperature of the pigment towards the substrate. Equivalent tests were carried out on substrates coated with a more or less thick silicon dioxide-based protective layer. Figure 2 is a photograph on which four different samples were tested. Sample A corresponds to that shown in Figure 1, as explained above. Sample B corresponds to a Planilux® glass substrate on which was deposited by magnetron a 20 nm thick layer of silica before depositing a black mineral pigment and baking the substrate thus prepared in a furnace. gradient between 600 and 700 ° C. Sample C is identical to Sample B except that the silica layer is thicker (about 25 nm). Sample D is identical to samples B and C, except that the silica protective layer has a thickness of 70 nm. The deposition step of the black pigment is carried out under the same experimental conditions as those described above for the sample A. It is found by comparing these different samples that the effect of the protective layer is noticeable: even for a weak Silica layer thickness, the gray tint decreases sharply and appears only weaker for high firing temperatures. By increasing the thickness of the protective layer, the gray tint disappears completely even at a high firing temperature of the order of 700 ° C. Example 2: Figure 3 shows a printed pattern according to the method of the present invention, with or without a silica protective layer. A black pigment layer was deposited by screen printing on two different substrates 2a and 2b; the substrate 2a corresponding to a clear glass panel and the substrate 2b corresponding to a clear glass panel on which a 25 μm silica layer has been deposited by magnetron.
    [0008] The screen printing screen used is 150.27 screen (150 thread / cm and 27 thread count). The average thickness of the (wet) layer of black pigments deposited on the glass is equal to 6 μm. The glasses were then introduced into a drying device equipped with infrared lamps operating at a temperature of the order of 145 to 155 ° C in order to eliminate the organic medium.
    [0009] The pattern representing the figure visible in Figure 3 was then deposited by screen printing also on the two glasses containing the black pigment. The enamel used is white and composed of frit with bismuth oxide and titanium oxide pigment. After drying the enamel at a temperature between 145 and 155 ° C, the glasses were fired at a standard quenching temperature of about 655 ° C.
    [0010] Non-fixed pigments are removed by brushing and washing with water. The tinting of the glass was prevented by means of the protective layer 902 previously deposited on one of the substrates. Example 3 A black mineral pigment was printed on different glasses coated with a layer containing SO2, the process used being the same as in Example 1. The layers used were deposited by various processes (magnetron (A), Chemical Vapor Deposition (B) "CVD" as well as a combination of these two techniques (C) Figure 4 shows the 3 types of layered glasses on which the black pigment was deposited The glasses were then washed and baked a temperature of 650 ° C.
    [0011] These different layered glasses (containing 902) made it possible to prevent the migration of the black pigment on the surface of the glass.
    权利要求:
    Claims (17)
    [0001]
    REVENDICATIONS1. A method of manufacturing a one-way vision glass panel comprising one or more discrete enamel patterns composed of a plurality of precisely coincidental layers, characterized in that: a) at least one layer of glass is deposited on the glass substrate; protection based on oxides of a thickness greater than or equal to 10 nm, b) depositing on the protective layer at least two layers of different composition, the composition of one of the layers containing at least one mineral pigment and being free from glass frit, the composition of the other layer being an enamel containing at least one glass frit and at least one mineral pigment of a different color from that of the glass frit-free layer, the frit-free layer of glass being deposited on all or part of the surface of the panel and the enamel layer being deposited by screen printing in the form of the desired pattern or patterns, c) the panel coated with said layers is heated to no temperature sufficient to cook the enamel, and d) the non-enamel-fixed pigments located outside the pattern (s), the pigment particles (s) and the glass frit particles are removed. having a similar size, especially a particle size distribution such that 50% of the particles have a size less than 7 pm.
    [0002]
    2. Method according to claim 1 characterized in that deposited on the protective layer of the glass frit-free layer to a thickness of between 4 and 15 pm, then is deposited by screen printing the enamel layer to a thickness of between 20 and 100 cm.
    [0003]
    3. Method according to claim 1 characterized in that deposited on the protective layer enamel layer to a thickness of between 10 and 100 pm, then depositing the glass frit-free layer to a thickness between 4 and 30 pm.
    [0004]
    4. Method according to one of claims 1 to 3 characterized in that the protective layer deposited in step a) is a layer of silicon oxide or titanium oxide.
    [0005]
    5. Method according to the preceding claim characterized in that the protective layer is a layer of silicon oxide deposited by magnetron.
    [0006]
    6. Method according to one of claims 1 to 5 characterized in that the thickness of the protective layer is between 10 and 150 nm, preferably between 20 and 100 nm.
    [0007]
    7. Method according to one of the preceding claims characterized in that step a) consists of depositing two successive layers of protection of different nature and thickness.
    [0008]
    8. Method according to one of claims 1 to 7 characterized in that the inorganic pigment used in the glass frit-free layer is chosen from pigments which make it possible to impart a black color after the drying step.
    [0009]
    9. Process according to claim 8, characterized in that the pigment is based on chromium, iron, manganese, copper and / or cobalt, preferably in the form of oxides or sulphides.
    [0010]
    10. Method according to one of claims 1 to 9, characterized in that the glass frit is free of lead oxide Pb0.
    [0011]
    11. The method of claim 10 characterized in that the glass frit is a borosilicate based on bismuth oxide Bi203 and / or zinc oxide ZnO.
    [0012]
    12. Process according to claim 10, characterized in that the glass frit contains 35 to 75% by weight of 902 and 20 to 40% by weight of Bi 2 O 3, advantageously 25 to 30% or 4 to 10% by weight of ZnO.
    [0013]
    13. Method according to one of claims 11 or 12, characterized in that the glass frit containing Bi203 has a softening temperature ranging from 550 to 580 ° C, preferably is equal to 568 ° C, and the frit containing ZnO has a softening temperature below 600 ° C.
    [0014]
    14. Method according to one of claims 1 to 13, characterized in that the mineral pigment of the enamel has a different color of the pigment used in the glass frit-free layer and preferably gives a different color of the black.
    [0015]
    15. The method as claimed in claim 14, characterized in that the pigment of the enamel layer is chosen from pigments which make it possible to impart a white color after the drying step and is preferably based on TiO 2.
    [0016]
    16. A method according to claim 14, characterized in that the pigment used in the enamel layer is of a different color than white, and is for example based on Cr203, Co304, or Fe203.
    [0017]
    17. Method according to one of claims 1 to 16, characterized in that the proportion of pigments in the composition of enamel ranges from 5 to 25% by weight, preferably 10 to 20%.
    类似技术:
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    同族专利:
    公开号 | 公开日
    JP2017515776A|2017-06-15|
    WO2015162375A1|2015-10-29|
    EP3134366A1|2017-03-01|
    FR3020360B1|2016-05-06|
    KR20160145597A|2016-12-20|
    EP3134366B1|2019-01-16|
    CN106458713A|2017-02-22|
    AU2015250663A2|2016-12-15|
    AU2015250663B2|2018-07-05|
    US20170044656A1|2017-02-16|
    AU2015250663A1|2016-12-01|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2012172269A1|2011-06-17|2012-12-20|Saint-Gobain Glass France|Process for manufacturing a glass substrate comprising printed enamel patterns|
    JPH10104419A|1996-10-01|1998-04-24|Dainippon Printing Co Ltd|Color filter and its manufacture|CN108137387B|2015-10-23|2021-08-31|皮尔金顿集团有限公司|Method of manufacturing glazing, and glazing produced thereby|
    FR3052769B1|2016-06-15|2018-07-13|Saint-Gobain Glass France|GLASS SHEET WITH EMAIL REFLECTING INFRARED RADIATION|
    CN107382089B|2017-05-26|2018-07-27|广东先朗照明有限公司|A kind of technique of glass surface graphic-print|
    EP3406577A1|2017-05-26|2018-11-28|Guangdong Shone Lighting Co., Ltd|Glass surface pattern printing process|
    KR20210067331A|2019-11-29|2021-06-08|쌩-고벵 글래스 프랑스|Chemically durable, Low-E coating compatible black enamel composition|
    法律状态:
    2015-04-04| PLFP| Fee payment|Year of fee payment: 2 |
    2015-10-30| PLSC| Search report ready|Effective date: 20151030 |
    2016-04-20| PLFP| Fee payment|Year of fee payment: 3 |
    2017-04-21| PLFP| Fee payment|Year of fee payment: 4 |
    2018-04-25| PLFP| Fee payment|Year of fee payment: 5 |
    2020-01-10| ST| Notification of lapse|Effective date: 20191205 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1453709A|FR3020360B1|2014-04-24|2014-04-24|METHOD FOR MANUFACTURING GLASS SUBSTRATE WITH PRINTED PATTERNS AND PROTECTIVE UNDERLAYER FOR SINGLE-SENSE VISION|FR1453709A| FR3020360B1|2014-04-24|2014-04-24|METHOD FOR MANUFACTURING GLASS SUBSTRATE WITH PRINTED PATTERNS AND PROTECTIVE UNDERLAYER FOR SINGLE-SENSE VISION|
    US15/305,547| US20170044656A1|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
    AU2015250663A| AU2015250663B2|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
    CN201580020960.7A| CN106458713A|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
    PCT/FR2015/051079| WO2015162375A1|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
    EP15725771.8A| EP3134366B1|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
    JP2016563844A| JP2017515776A|2014-04-24|2015-04-21|Method for producing glass substrate for one-way viewing provided with printed pattern and protective lower layer|
    KR1020167029068A| KR20160145597A|2014-04-24|2015-04-21|Process for manufacturing a glass substrate equipped with printed patterns and a protective underlayer for one-way vision|
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